Stabilization of the Metastable Lead Iodide Perovskite Phase via Surface Functionalization
نویسندگان
چکیده
منابع مشابه
Stabilization of the Cubic Crystalline Phase in Organometal Halide Perovskite Quantum Dots via Surface Energy Manipulation.
Surface functionalization of nanoscale materials has a significant impact on their properties. We have demonstrated the effect of different passivating ligands on the crystal phase of organometal halide perovskite quantum dots (PQDs). Using static and dynamic spectroscopy, we studied phase transitions in CH3NH3PbBr3 PQDs ligated with either octylaminebromide (P-OABr) or 3-aminopropyl triethoxys...
متن کاملStructures, Phase Transitions and Tricritical Behavior of the Hybrid Perovskite Methyl Ammonium Lead Iodide
We have examined the crystal structures and structural phase transitions of the deuterated, partially deuterated and hydrogenous organic-inorganic hybrid perovskite methyl ammonium lead iodide (MAPbI3) using time-of-flight neutron and synchrotron X-ray powder diffraction. Near 330 K the high temperature cubic phases transformed to a body-centered tetragonal phase. The variation of the order par...
متن کاملHigh Chloride Doping Levels Stabilize the Perovskite Phase of Cesium Lead Iodide.
Cesium lead iodide possesses an excellent combination of band gap and absorption coefficient for photovoltaic applications in its perovskite phase. However, this is not its equilibrium structure under ambient conditions. In air, at ambient temperature it rapidly transforms to a nonfunctional, so-called yellow phase. Here we show that chloride doping, particularly at levels near the solubility l...
متن کاملCorrigendum: Structures, Phase Transitions and Tricritical Behavior of the Hybrid Perovskite Methyl Ammonium Lead Iodide
‘Lattice parameters determined from the synchrotron X-ray diffraction scans of the cubic 200 and tetragonal 220/004 Bragg peaks. Fits to the cubic lattice parameter (black solid line) and the average tetragonal lattice parameter (= 2atet + ctet)/3 (blue solid line), were used to determine the linear coefficients of thermal expansion of 1.95 × 10−4 K−1 (cubic) and 2.66 × 10−4 K−1 (tetragonal). T...
متن کاملPhotoluminescence Blinking of Single-Crystal Methylammonium Lead Iodide Perovskite Nanorods Induced by Surface Traps
Photoluminescence (PL) of organometal halide perovskite materials reflects the charge dynamics inside of the material and thus contains important information for understanding the electro-optical properties of the material. Interpretation of PL blinking of methylammonium lead iodide (MAPbI3) nanostructures observed on polycrystalline samples remains puzzling owing to their intrinsic disordered ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Nano Letters
سال: 2017
ISSN: 1530-6984,1530-6992
DOI: 10.1021/acs.nanolett.7b01500